Which actor became the first major brand ambassador for a luxury watch company specifically to wear their timepiece in a James Bond film?

The film industry has increasingly turned to major brand ambassador deals to promote blockbuster releases. These partnerships between studios and corporations have created some of the most memorable marketing campaigns in entertainment history. How well do you know the strategic brand ambassadorships that helped promote major film releases? Test your knowledge of these powerful marketing collaborations that bridged the gap between Hollywood and corporate America.

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Pierce Brosnan for Omega in 'GoldenEye' (1995)
Sean Connery for Rolex in 'Dr. No' (1962)
Roger Moore for Seiko in 'Live and Let Die' (1973)
Daniel Craig for Omega in 'Casino Royale' (2006)