Which packaging innovation first introduced phase-change materials specifically designed for temperature-sensitive scientific specimens?

In the world of scientific research and laboratory supplies, packaging innovation is crucial for ensuring sample integrity, reducing contamination risk, and enhancing sustainability. This poll tests your knowledge about a groundbreaking packaging technology that revolutionized how sensitive scientific materials are transported and stored. Can you identify the correct innovation that changed scientific logistics forever?

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VacuTherm™ by CryoScience (1998) - Using vacuum insulation panels with embedded temperature sensors
ThermaCore™ by Fisher Scientific (2003) - Employing microencapsulated phase-change materials that maintain 2-8°C for 72+ hours
CryoShield™ by Merck (2001) - Utilizing liquid nitrogen absorption technology in recyclable composite materials
BioPreserve™ by BD (2005) - Featuring radiofrequency-responsive gel polymers that stabilize at precise temperatures